Bipolar spin filter in a quantum dot molecule

We show that the tunable hybridization between two lateral quantum dots connected to non-magnetic current leads in a `hanging-dot' configuration that can be used to implement a bipolar spin filter. The competition between Zeeman, exchange interaction, and interdot tunneling (molecular hybridization) yields a singlet-triplet transition of the double dot {\it ground state} that allows spin filtering in Coulomb blockade experiments. Its generic nature should make it broadly useful as a robust bidirectional spin polarizer.Comment: 5 pages, 3 figures (to appear in Appl. Phys. Lett.

Instrumental variables quantile regression for panel data with measurement errors

This paper develops an instrumental variables estimator for quantile regression in panel data with fixed effects. Asymptotic properties of the instrumental variables estimator are studied for large N and T when Na/T ! 0, for some a > 0. Wald and Kolmogorov-Smirnov type tests for general linear restrictions are developed. The estimator is applied to the problem of measurement errors in variables, which induces endogeneity and as a result bias in the model. We derive an approximation to the bias in the quantile regression fixed effects estimator in the presence of measurement error and show its connection to similar effects in standard least squares models. Monte Carlo simulations are conducted to evaluate the finite sample properties of the estimator in terms of bias and root mean squared error. Finally, the methods are applied to a model of firm investment. The results show interesting heterogeneity in the Tobin’s q and cash flow sensitivities of investment. In both cases, the sensitivities are monotonically increasing along the quantiles

Visible light-mediated gold-catalysed carbon(sp2)-carbon(sp) cross-coupling.

A dual photoredox and gold-catalysed cross-coupling reaction of alkynyltrimethylsilanes and aryldiazonium tetrafluoroborates is described. The reaction proceeds through visible-light mediated oxidative addition of aryldiazoniums, transmetalation of alkynyltrimethylsilanes and aryl-alkynyl reductive elimination. Exclusive selectivity for silyl-substituted alkynes is observed, with no reactivity observed for terminal alkynes